Metal-Organic Skeleton-Derived W-Doped Ga₂O₃-NC Catalysts for Aerobic Oxidative Dehydrogenation of <i>N</i>-Heterocycles.

ABSTRACT: N-heterocycles with quinoline structures hold significant importance within the chemical and pharmaceutical industries. However, achieving their efficient transformations remains a vital yet challenging endeavor. Herein, a series of W-doped Ga₂O₃-NC catalysts were synthesized using a Ga-MOF-derived strategy through a simple solvothermal method, with a remarkably high activity and selectivity towards the oxidative dehydrogenation of N-heterocycles. Furthermore, the MOF-derived W-doped Ga₂O₃-NC catalysts exhibit remarkable substrate tolerance and recyclability. The outstanding catalytic activity was attributed to the robust synergistic interaction between the W species and the Ga₂O₃-NC carrier, which facilitates

SUBMITTER: Zhang F 

PROVIDER: S-EPMC11477574 | biostudies-literature | 2024 Sep

REPOSITORIES: biostudies-literature