Unveiling the Photodegradation Mechanism of Monochlorinated Naphthalenes under UV-C Irradiation: Affecting Factors Analysis, the Roles of Hydroxyl Radicals, and DFT Calculation.

ABSTRACT: Polychlorinated naphthalenes (PCNs) are a new type of persistent organic pollutant (POP) characterized by persistence, bioaccumulation, dioxin-like toxicity, and long-range atmospheric transport. Focusing on one type of PCN, monochlorinated naphthalenes (CN-1, CN-2), this study aimed to examine their photodegradation in the environment. In this work, CN-1 and CN-2 were employed as the model pollutants to investigate their photodegradation process under UV-C irradiation. Factors like the pH, initial concentrations of CN-1, and inorganic anions were investigated. Next, the roles of hydroxyl radicals (^•OH), superoxide anion radicals (O₂^•-), and singlet oxygen (¹O₂) in the photodegradation process were discussed and proposed via theory com

SUBMITTER: Yu Y 

PROVIDER: S-EPMC11477601 | biostudies-literature | 2024 Sep

REPOSITORIES: biostudies-literature