On-chip phonon-enhanced IR near-field detection of molecular vibrations.

ABSTRACT: Phonon polaritons - quasiparticles formed by strong coupling of infrared (IR) light with lattice vibrations in polar materials - can be utilized for surface-enhanced infrared absorption (SEIRA) spectroscopy and even for vibrational strong coupling with nanoscale amounts of molecules. Here, we introduce and demonstrate a compact on-chip phononic SEIRA spectroscopy platform, which is based on an h-BN/graphene/h-BN heterostructure on top of a metal split-gate creating a p-n junction in graphene. The metal split-gate concentrates the incident light and launches hyperbolic phonon polaritons (HPhPs) in the heterostructure, which serves simultaneously as SEIRA substrate and room-temperature infrared detector. When thin organic layers are deposited directly on top of the heterostructure, we observ

SUBMITTER: Bylinkin A 

PROVIDER: S-EPMC11484778 | biostudies-literature | 2024 Oct

REPOSITORIES: biostudies-literature