Permeable void-free interface for all-solid-state alkali-ion polymer batteries.

ABSTRACT: All-solid-state batteries suffer from a loss of contact between the electrode and electrolyte particles, leading to poor cyclability. Here, a void-free ion-permeable interface between the solid-state polymer electrolyte and electrode is constructed in situ during cycling using charge/discharge voltage as the stimulus. During the charge-discharge, the permeation phase fills the voids at the interface and penetrates the electrode, forming strong bonds with the cathode and effectively mitigating the contact problem. Our all-solid-state potassium ion polymer batteries maintain high Coulombic efficiency more than 2000 cycles at a high operating voltage of 4.5 volt and stably cycle more than 500 cycles even at 4.6 volt. Our rational design for mitigating the contact problem is versatile, as demo

SUBMITTER: Lyu W 

PROVIDER: S-EPMC11488535 | biostudies-literature | 2024 Oct

REPOSITORIES: biostudies-literature