Fabrication of monodisperse micron-sized and aldehyde-functionalized microspheres coating with covalent organic framework for efficient and rapid removal of copper ions from wastewater.

ABSTRACT: Covalent organic frameworks (COFs) possess an excellent ability for absorbing heavy metals, but their uneven particle size, difficult separation, and poor dispersion limit their wide application in the treatment of heavy metal pollution. In this paper, a monodisperse poly(4-allyloxybenzaldehyde-co-divinylbenzene) microsphere (denoted as PAD) was prepared with 4-allyloxybenzaldehyde as a functional monomer and divinylbenzene (DVB) as a crosslinker by one-step seed swelling polymerization. Subsequently, oxalyldihydrazide (ODH) and 2,4,6-trihydroxybenzene-1,3,5-tricarbaldehyde (Tp) were chosen as the precursors for coating the COF layer onto the surface of PAD through a one-pot method. The resulting monodisperse particles (diameter = 6.3 μm) with a core-shell structure were assigned as

SUBMITTER: Wang X 

PROVIDER: S-EPMC11499976 | biostudies-literature | 2024 Oct

REPOSITORIES: biostudies-literature