Light-Controlled Interconvertible Self-Assembly of Non-Photoresponsive Suprastructures.

ABSTRACT: Achieving light-induced manipulation of controlled self-assembly in nanosized structures is essential for developing artificially dynamic smart materials. Herein, we demonstrate an approach using a non-photoresponsive hydrogen-bonded (H-bonded) macrocycle to control the self-assembly and disassembly of nanostructures in response to light. The present system comprises a photoacid (merocyanine, 1-MEH), a pseudorotaxane formed by two H-bonded macrocycles, dipyridinyl acetylene, and zinc ions. The operation of such a system is examined according to the alternation of self-assembly through proton transfer, which is mediated by the photoacid upon exposure to visible light. The host-guest complexation between the macrocycle and bipyridium guests was investigated by NMR spectroscopy, and one of th

SUBMITTER: Yu W 

PROVIDER: S-EPMC11509933 | biostudies-literature | 2024 Oct

REPOSITORIES: biostudies-literature