Novel Thiourea Ligands-Synthesis, Characterization and Preliminary Study on Their Coordination Abilities.

ABSTRACT: Two series of polydentate N,O,S-ligands containing thiourea fragments attached to a p-cresol scaffold, unsymmetrical mono-acylated bis-amines and symmetrical bis-thioureas, are obtained by common experiments. It is observed that the reaction output is strongly dependent on both bis-amine and thiocarbamic chloride substituents. The products are characterized by 1D and 2D NMR spectra in solution and by single crystal XRD. A preliminary study on the coordination abilities of selected products is performed by ITC at around neutral media.

SUBMITTER: Todorova SE 

PROVIDER: S-EPMC11510064 | biostudies-literature | 2024 Oct

REPOSITORIES: biostudies-literature