Sub-10 nm PdNi@PtNi Core-Shell Nanoalloys for Efficient Ethanol Electro-Oxidation.

ABSTRACT: By controlling the structure and composition of Pt-based nanoalloys, the ethanol oxidation reaction (EOR) performances of Pt alloy catalysts can be effectively improved. Herein, we successfully synthesis sub-10 nm PdNi@PtNi nanoparticles (PdNi@PtNi NPs) with a core-shell structure by a one-pot method. The sub 10 nm core-shell nanoparticles possess more effective atoms and exhibit a synergistic effect which can lead to a shift in the d-band center and alter binding energies toward adsorbates. Due to the synergistic effect and unique core-shell structure, the PdNi@PtNi NP catalysts exhibit excellent electrocatalytic performance for ethanol oxidation reactions in alkaline, achieving 9.30 times more mass activity and 7.05 times more specific activity that of the state-of-the-art Pt/C catalysts

SUBMITTER: Su Q 

PROVIDER: S-EPMC11510317 | biostudies-literature | 2024 Oct

REPOSITORIES: biostudies-literature