Nonradiative Deactivation of the Fluorescent Ag₁₆-DNA and Ag₁₀-DNA Emitters: The Role of Water.

ABSTRACT: The luminescent quantum yield of silver-cluster emitters stabilized by short oligonucleotides (Ag_N-DNA) may be efficiently tuned by replacing nucleobases in their stabilization DNA matrices with analogues. In the present study, we proposed a valuable and straightforward theoretical methodology for assessing the photophysical behaviors emerging in Ag_N-DNA emitters after excitation. Using green Ag₁₀-DNA and near-IR Ag₁₆-DNA emitters we demonstrate how point guanine/inosine replacement could affect the photophysical rate constants of radiative/nonradiative processes. The main deactivation channel of the fluorescence of Ag₁₆-DNA is intersystem crossing, which is in line with experimental data, whereas for Ag₁₀-DNA the calculatio

SUBMITTER: Ramazanov RR 

PROVIDER: S-EPMC11514010 | biostudies-literature | 2024 Oct

REPOSITORIES: biostudies-literature