Self-Assembled Nanostructure of Ionic Sn(IV)porphyrin Complex Based on Multivalent Interactions for Photocatalytic Degradation of Water Contaminants.

ABSTRACT: [Sn(H₂PO₄)₂(TPy^HP)](H₂PO₄)₄∙6H₂O (2), an ionic tin porphyrin complex, was synthesized from the reaction of [Sn(OH)₂TPyP] (1) with a dilute aqueous solution of a polyprotic acid (H₃PO₄). Complex 2 was fully characterized using various spectroscopic methods, such as X-ray single-crystal crystallography, ¹H NMR spectroscopy, elemental analysis, FTIR spectroscopy, UV-vis spectroscopy, emission spectroscopy, EIS mass spectrometry, PXRD, and TGA analysis. The crystal structure of 2 reveals that the intermolecular hydrogen bonds between the peripheral pyridinium groups and the axially coordinated dihydrogen phosphate ligands are the

SUBMITTER: Shee NK 

PROVIDER: S-EPMC11539948 | biostudies-literature | 2024 Sep

REPOSITORIES: biostudies-literature