Contributions of Colloidal Forces to the Heterogeneous Separation of Stable Oil-In-Water Emulsions.
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ABSTRACT: We use theory to study the distribution of spherical emulsion oil droplets in water near a lipophilic surface as a guideline for designing membranes for oil/water phase separation. Heterogeneous phase separations are shown in our laboratory using hydrophilic and hydrophobic membrane designs, where the affinity of the membrane surface to one of the phases in the mixture locally increases its concentration. Considering a colloidal emulsion (nano- to microemulsions) of spherical and noncoalescing droplets, we assess the contribution of colloidal forces, i.e., van der Waals, electrical double layer, and hydrophobic interactions and the finite size of the droplets to the accumulation of spherical emulsion droplets near a surface. We use our theory to study an experiment-inspired case study and
SUBMITTER: Bar-On R
PROVIDER: S-EPMC11542182 | biostudies-literature | 2024 Nov
REPOSITORIES: biostudies-literature
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