A d¹⁰-Cd Cluster Containing Sandwich-Type Arsenotungstate Exhibiting Fluorescent Recognition of Carcinogenic Dye in Methanol.

ABSTRACT: A d¹⁰-Cd cluster containing sandwich-type arsenotungstate [C₃H₁₂N₂]₆[Cd₄Cl₂(B-α-AsW₉O₃₄)₂] was synthesized and its structure characterized through elemental analyses, X-ray powder diffraction (XRPD), IR spectroscopy, X-ray photoelectron spectroscopy (XPS), and single-crystal X-ray diffraction. The X-ray analysis revealed that the molecular unit of the compound consists of a captivating tetra-Cd-substituted sandwich-type polyoxoanion, accompanied by six elegantly protonated 1,2-diaminopropane as counter ions. The further novelty of the tetranuclear cadmium cluster lies in its occupied chlorine atom sites. This makes it highly susceptible to coordinate reactions with nitrogen

SUBMITTER: Wang F 

PROVIDER: S-EPMC11547473 | biostudies-literature | 2024 Nov

REPOSITORIES: biostudies-literature