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Heterogeneous Catalytic Ozonation of Pharmaceuticals: Optimization of the Process by Response Surface Methodology.


ABSTRACT: Batch heterogeneous catalytic ozonation experiments were performed using commercial and synthesized nanoparticles as catalysts in aqueous ozone. The transferred ozone dose (TOD) ranged from 0 to 150 μM, and nanoparticles were added in concentrations between 0 and 1.5 g L-1, with all experiments conducted at 20 °C and a total volume of 240 mL. A Ce-doped TiO2 catalyst (1% molar ratio of Ce/Ti) was synthesized via the sol-gel method. Response surface methodology (RSM) was applied to identify the most significant factors affecting the removal of selected pharmaceuticals, with TOD emerging as the most critical variable. Higher TOD resulted in greater removal efficiencies. Furthermore, it was found that the commercially available metal oxides α-Al2O3,

SUBMITTER: Tsiarta N 

PROVIDER: S-EPMC11547524 | biostudies-literature | 2024 Oct

REPOSITORIES: biostudies-literature