Re-examination of the Claimed Isolation of Stable Noncyclic 1,2-Disulfoxides.

ABSTRACT: Re-examination of the claimed isolation and X-ray characterization of di-p-tolyl and dimesityl 1,2-disulfoxides from thermolysis of the corresponding aryl sulfinimines and thiosulfinates showed that the isolated disulfide dioxides are instead the well-known isomeric thiosulfonates, as confirmed by XAS, DART-MS, X-ray, IR and NMR methods. Concerns with the original X-ray structures are addressed. Our results agree with the DFT prediction of very weak diaryl 1,2-disulfoxide S-S bond dissociation enthalpies. For now, room-temperature-stable noncyclic 1,2-disulfoxides remain unknown.

SUBMITTER: Block E 

PROVIDER: S-EPMC11574841 | biostudies-literature | 2024 Nov

REPOSITORIES: biostudies-literature