Rare-earth metal complexes bearing electrophilic and nucleophilic carbon centres and their unique reactivity patterns towards pyridine derivatives.

ABSTRACT: The rare-earth metal dialkyl complexes (κ²-L¹)RE(CH₂SiMe₃)₂·(THF)₂ [RE = Lu(1a), Yb(1b), Er(1c), Y(1d), Dy(1e)] (L¹ = 1-(2-N-C₅H₁₀NCH₂CH₂)-3-(2,6-ⁱPr₂C₆H₃N[double bond, length as m-dash]CH)-C₈H₄N) and the rare-earth metal monoalkyl complexes (κ²-L¹)₂RE(CH₂SiMe₃)·(THF) _n [n = 0, RE = Lu(2a), Yb(2b); n = 1, Er(2c), Y(2d), Dy(2e)], (κ²-L²)₂RE(CH₂SiMe₃)·THF [RE = Yb(3a), Er(3b), Y(3c), Dy(3d), Gd(3e)] (L² = 1-(2-N-C₅H₁₀NCH

SUBMITTER: Wu W 

PROVIDER: S-EPMC11575488 | biostudies-literature | 2024 Dec

REPOSITORIES: biostudies-literature