Pnictogen-based vanadacyclobutadiene complexes.

ABSTRACT: The reactivity of the V[triple bond, length as m-dash]C ^t Bu multiple bonds in the complex (dBDI)V[triple bond, length as m-dash]C ^t Bu(OEt₂) (C) (dBDI^2- = ArNC(CH₃)CHC(CH₂)NAr, Ar = 2,6- ⁱ Pr₂C₆H₃) with unsaturated substrates such as N[triple bond, length as m-dash]CR (R = Ad or Ph) and P[triple bond, length as m-dash]CAd leads to the formation of rare 3d transition metal compounds featuring α-aza-vanadacyclobutadiene, (dBDI)V(κ²- C , N - ^t BuCC(R)N) (R = Ad, 1; R = Ph, 2) and β-phospha-vanadacyclobutadiene moieties, (dBDI)V(κ²- C , C - ^t Bu

SUBMITTER: Jafari MG 

PROVIDER: S-EPMC11575583 | biostudies-literature | 2024 Dec

REPOSITORIES: biostudies-literature