Amine Functionalization of Channels of Metal-Organic Frameworks for Effective Chemical Fixation of Carbon Dioxide: A Comparative Study with Three Newly Designed Porous Networks.

ABSTRACT: Catalytic transformation of CO₂ into value-added chemical products can provide an appropriate solution for the raising environmental issues. To date, various metal-organic frameworks (MOFs) with transition metal ions have been explored for CO₂ capture and conversion, but alkaline earth metal-based MOFs are comparatively less studied. Metal ions like Sr(II) having relatively large radius give rise to a high coordination number resulting in higher stability of the MOFs. Moreover, the introduction of N-rich functional group in organic linker like -NH₂, -CONH- and triazole into MOF backbone enhance their CO₂ capture and conversion efficiency. Herein, the effect of amine group on the catalytic efficiency of MOFs for CO₂ cycloaddition with e

SUBMITTER: Moi R 

PROVIDER: S-EPMC11633332 | biostudies-literature | 2024 Sep

REPOSITORIES: biostudies-literature