Crystal structure of <i>catena</i>-poly[[di-aqua-di-imida-zole-cobalt(II)]-μ<sub>2</sub>-2,3,5,6-tetra-bromo-benzene-1,4-di-carboxyl-ato].
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ABSTRACT: The asymmetric unit of the title compound, [Co(C8Br4O4)(C3H4N2)2(H2O)2] n or [Co(Br4bdc)(im)2(H2O)2] n , comprises half of CoII ion, tetra-bromo-benzene-dicarboxylate (Br4bdc2-), imidazole (im) and a water mol-ecule. The CoII ion exhibits a six-coordinated octa-hedral geometry with two oxygen atoms of the Br4bdc2- ligand, two oxygen atoms of the water mol-ecules, and two nitro-gen atoms of the im ligands. The carboxyl-ate group is nearly perpendicular to the benzene ring and shows monodentate coordination to the CoII ion. The CoII
SUBMITTER: Kumagai H
PROVIDER: S-EPMC11660475 | biostudies-literature | 2024 Oct
REPOSITORIES: biostudies-literature
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