Crystal structure of (μ₂-7-{[bis-(pyridin-2-ylmeth-yl)amino-1κ³ <i>N</i>,<i>N</i>',<i>N</i>'']meth-yl}-5-chloro-quinolin-8-olato-2κ<i>N</i>;1:2κ² <i>O</i>)tri-chlorido-1κ<i>Cl</i>,2κ² <i>Cl</i>-dizinc(II).

ABSTRACT: The title compound, [Zn₂(C₂₂H₁₈ClN₄O)Cl₃], is a dinuclear zinc(II) complex with three chlorido ligands and one penta-dentate ligand containing quinolin-8-olato and bis-(pyridin-2-ylmeth-yl)amine groups. One of the two Zn^II atom adopts a tetra-hedral geometry and coordinates two chlorido ligands with chelate coord-ination of the N and O atoms of the quinolin-8-olato group in the ligand. The other Zn^II atom adopts a distorted trigonal-bipyramidal geometry, and coordinates one chlorido-O atom of the quinolin-8-olato group and three N atoms of the bis-(pyridin-2-ylmeth-yl)amine unit. In the crystal, two mol-ecules are associated through a pair of inter-molecular C-H⋯Cl hydrogen bonds, forming a dimer with an R

SUBMITTER: Kubono K 

PROVIDER: S-EPMC11660488 | biostudies-literature | 2024 Oct

REPOSITORIES: biostudies-literature