Synthesis, crystal structure and properties of μ-tetra-thio-anti-monato-bis-[(cyclam)zinc(II)] perchlorate 0.8-hydrate.

ABSTRACT: The reaction of Zn(ClO₄)₂·6H₂O with Na₃SbS₄·9H₂O in a water/aceto-nitrile mixture leads to the formation of the title compound, (μ-tetra-thio-anti-monato-κ² S:S')bis-[(1,4,8,11-tetra-aza-cyclo-tetra-decane-κ⁴ N)zinc(II)] perchlorate 0.8-hydrate, [Zn₂(SbS₄)(C₁₀H₂₄N₄)₂]ClO₄·0.8H₂O or [(Zn-cyclam)₂(SbS₄)]⁺[ClO₄]^-·0.8H₂O. The asymmetric unit consists of two crystallographically independent [SbS₄]^3- anions, two independent perchlorate anions and two independent water mol-ecules as well as four crystallographically

SUBMITTER: Nather C 

PROVIDER: S-EPMC11660490 | biostudies-literature | 2024 Oct

REPOSITORIES: biostudies-literature