A new mesoporous Ce-Mn-LDH-based Co-MOF nano-composite for the green synthesis of tetrazoloquinazolines.

ABSTRACT: Tannic acid (TA), as a plant polyphenol, has many active sites for chelation with metals, so TA-oligomers (TA-Olig) were used for the first time as ligands on the surface of Ce-Mn-LDH to prepare the layered double hydroxide-based metal-organic framework (Ce-Mn-LDH@CPTMS@TA-Olig@Co-MOF = E) nanocomposite. In this regard, a homogeneous water/ethanol solution was prepared by sol-gel method using polyethylene glycol and ammonia solution, and then TA was converted into a set of oligomers in the presence of formaldehyde. In the next step, Ce-Mn-LDH was prepared in a ratio of 1 : 4 of Ce to Mn, modified with 3-chloropropylmethoxysilane, functionalized by TA-Olig, and then cobalt salt was used to prepare E. Finally, the structure of E was determined by FT-IR, ICP, XRD, BET, EDX, SEM, SEM-mapping,

SUBMITTER: Javadi S 

PROVIDER: S-EPMC11668168 | biostudies-literature | 2025 Feb

REPOSITORIES: biostudies-literature