Transition-Metal-Free Thioboration of Terminal Alkynes.

ABSTRACT: We present a new type of elementoboration reaction, the thioboration of terminal alkynes. This method enables highly controllable regio-/stereo-/chemoselective cis- and trans-thioboration on demand, affording synthetically versatile and densely functionalized vinyl boron/vinyl sulfide derivatives in a straightforward manner without the need for a transition-metal catalyst.

SUBMITTER: Matsuyama T 

PROVIDER: S-EPMC11672135 | biostudies-literature | 2024 Dec

REPOSITORIES: biostudies-literature