Out-of-plane coordination of iridium single atoms with organic molecules and cobalt-iron hydroxides to boost oxygen evolution reaction.

ABSTRACT: Advancements in single-atom-based catalysts are crucial for enhancing oxygen evolution reaction (OER) performance while reducing precious metal usage. A comprehensive understanding of underlying mechanisms will expedite this progress further. Here we report Ir single atoms coordinated out-of-plane with dimethylimidazole (MI) on CoFe hydroxide (Ir₁/(Co,Fe)-OH/MI). This Ir₁/(Co,Fe)-OH/MI catalyst, which was prepared using a simple immersion method, delivers ultralow overpotentials of 179 mV at a current density of 10 mA cm^-2 and 257 mV at 600 mA cm^-2 as well as an ultra-small Tafel slope of 24 mV dec^-1. Furthermore, Ir₁/(Co,Fe)-OH/MI has a total mass activity exceeding that of commercial IrO₂ by a factor of 58.4. Ab

SUBMITTER: Zhao J 

PROVIDER: S-EPMC11750697 | biostudies-literature | 2025 Jan

REPOSITORIES: biostudies-literature