Separating nanobubble nucleation for transfer-resistance-free electrocatalysis.

ABSTRACT: Electrocatalytic gas-evolving reactions often result in bubble-covered surfaces, impeding the mass transfer to active sites. Such an issue will be worsened in practical high-current-density conditions and can cause sudden cell failure. Herein, we develop an on-chip microcell-based total-internal-reflection-fluorescence-microscopy to enable operando imaging of bubbles at sub-50 nm and dynamic probing of their nucleation during hydrogen evolution reaction. Using platinum-interfacial metal layer-graphene as model systems, we demonstrate that the strong binding energy between interfacial metal layer and graphene-evidenced by a reduced metal-support distance and enhanced charge transfer-facilitates hydrogen spillover from platinum to the graphene support due to lower energy barriers compared to

SUBMITTER: Guo S 

PROVIDER: S-EPMC11754753 | biostudies-literature | 2025 Jan

REPOSITORIES: biostudies-literature