<i>In Situ</i> Assembly of 3-(Tetrazol-5-yl)triazole Complexes with Ammonium Perchlorate for High-Performance Energetic Composites.

ABSTRACT: Advanced energetic composites possess promising properties and wide-ranging applications in explosives and propellants. Nonetheless, most metal-based energetic composites present significant challenges due to surface oxidation and low-pressure output. This study introduces a facile in situ method to develop energetic composites Cutztr@AP through the intermolecular assembly of nitrogen-rich energetic coordination polymers and high-energy oxidant ammonium perchlorate (AP). Morphological analysis reveals the unique structure of Cutztr@AP, where Cutztr is distributed throughout the interior and surface of the AP particles. The nonisothermal thermodynamic analysis reveals a heat release of 2378.2 J g^-1 for Cutztr@AP₂, outperforming the Cutztr/AP₂ achieved

SUBMITTER: Meng KJ 

PROVIDER: S-EPMC11758780 | biostudies-literature | 2025 Jan

REPOSITORIES: biostudies-literature