Ultrafast Luminescence Detection with Selective Adsorption of Carbon Disulfide in a Gold(I) Metal-Organic Framework.

ABSTRACT: Although a widely used and important industrial chemical, carbon disulfide (CS₂) poses a number of hazards due to its volatility and toxicity. As such, the development of multifunctional materials for the selective capture and easy recognition of CS₂ is one of the crucial issues. Herein, we demonstrate completely selective CS₂ adsorption among trials involving H₂O, alcohols, volatile organic compounds (including thiol derivatives), N₂, H₂, O₂, CH₄, CO, NO, and CO₂. We also showcase its fine detection using remarkable luminescent response in a gold(I)-based metal-organic framework (MOF) of {Zn^II(pz)[Au^I(CN)₂]₂} (pz=pyrazine; 1) with a two-fold interp

SUBMITTER: Yoshino H 

PROVIDER: S-EPMC11773104 | biostudies-literature | 2025 Jan

REPOSITORIES: biostudies-literature