Chloride Treatments Improve Zinc Telluride Absorbers for Photoelectrochemical Carbon Dioxide Reduction.

ABSTRACT: Utilizing sunlight for photoelectrochemical carbon dioxide reduction reaction (PEC CO₂ RR) is a carbon-neutral path to valuable liquid fuels. Higher quality photoabsorbers are needed to improve the efficiency of the PEC CO₂ RR process. We show how the optoelectronic properties of sputtered ZnTe absorbers can be improved for this purpose via chloride treatments. MnCl₂ and MgCl₂ heat treatments recrystallize ZnTe absorbers to enlarge grains and improve photoluminescence. These material improvements result in the highest PEC CO₂ RR photocurrent density reported for planar ZnTe and >50% Faradaic efficiency to CO formation with diaryliodonium additive in the solution. These results pave the way to integration of polycrystalline thin-film ph

SUBMITTER: Muzzillo CP 

PROVIDER: S-EPMC11775882 | biostudies-literature | 2025 Jan

REPOSITORIES: biostudies-literature