Bithiophene Imide-Based Self-Assembled Monolayers (SAMs) on NiOx for High-Performance Tin Perovskite Solar Cells Fabricated Using a Two-Step Approach.

ABSTRACT: Three new bithiophene imide (BTI)-based organic small molecules, BTI-MN-b4 (1), BTI-MN-b8 (2), and BTI-MN-b16 (3), with varied alkyl side chains, were developed and employed as self-assembled monolayers (SAMs) applied to NiOx films in tin perovskite solar cells (TPSCs). The NiOx layer has the effect of modifying the hydrophilicity and the surface roughness of ITO for SAM to uniformly deposit on it. The side chains of the SAM molecules play a vital role in the formation of a high-quality perovskite layer in TPSCs. The single crystal structure of BTI-MN-b8 (2) was successfully obtained, indicating that a uniform SAM can be formed on the NiOx/ITO substrate with an appropriate size of the alkyl side chain. By combining BTI-MN-b8 (<

SUBMITTER: Velusamy A 

PROVIDER: S-EPMC11783363 | biostudies-literature | 2025 Jan

REPOSITORIES: biostudies-literature