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Boosting the O<sub>2</sub>-to-H<sub>2</sub>O<sub>2</sub> Selectivity Using Sn-Doped Carbon Electrocatalysts: Towards Highly Efficient Cathodes for Actual Water Decontamination.


ABSTRACT: The high cost and often complex synthesis procedure of new highly selective electrocatalysts (particularly those based on noble metals) for H2O2 production are daunting obstacles to penetration of this technology into the wastewater treatment market. In this work, a simple direct thermal method has been employed to synthesize Sn-doped carbon electrocatalysts, which showed an electron transfer number of 2.04 and outstanding two-electron oxygen reduction reaction (ORR) selectivity of up to 98.0 %. Physicochemical characterization revealed that this material contains 1.53 % pyrrolic nitrogen, which is beneficial for the production of H2O2, and -C≡N functional group, which is advantageous for H+ transport. Moreover, the high volume ratio o

SUBMITTER: Zhao L 

PROVIDER: S-EPMC11789999 | biostudies-literature | 2025 Feb

REPOSITORIES: biostudies-literature