High-valent oxovanadium metallosupramolecular species as catalysts for the oxidation of benzyl alcohol derivatives.

ABSTRACT: Coordination-driven synthesis has been successfully utilized to prepare vanadium-based metallosupramolecular species. By systematically varying synthesis methods and reaction conditions, two series of isostructural oxovanadium(v) coordination polymers [VO(SIH)(OR)] _n (where SIH^2- represents salicylaldehyde isonicotinoylhydrazonate, and R corresponds to CH₃ (1β·0.25CH₃OH), C₂H₅ (2α and 2β·0.25C₂H₅OH), C₃H₇ (3α), C₄H₉ (4α and 4β), and C₅H₁₁ (5β)), were synthesized. Additionally, a phase-pure tetranuclear compound [VO(SIH)(OCH₃)]₄·4CH₃OH (1t·4CH₃OH) was also prepared. In these compounds the

SUBMITTER: Topic E 

PROVIDER: S-EPMC11791748 | biostudies-literature | 2025 Jan

REPOSITORIES: biostudies-literature