High-Performance Sunlight-Induced Polymerized Hydrogels and Applications in 3D and 4D Printing.
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ABSTRACT: Currently, there are only few reports on water-soluble photoinitiating systems. In this study, a highly water-soluble organic dye i.e. sodium (E)-3,3'-((4-(2-(3-methylbenzo[d]thiazol-3-ium-2-yl)vinyl)phenyl)azanediyl)dipropionate iodide, was synthesized and served as a photoinitiator. Notably, this water-soluble initiator, at a low concentration of just 0.01 wt%, demonstrates a high photoinitiation ability, with some hydrogel formulations achieving nearly 100% double bond conversion under sunlight. Photopolymerization kinetics were monitored using Real-Time Fourier Transform Infrared. To explore the complex chemical principles of radical polymerization, UV-visible absorption and fluorescence spectroscopy, steady-state photolysis, fluorescence quenching experiments and cyclic voltammetry we
SUBMITTER: Feng J
PROVIDER: S-EPMC11798354 | biostudies-literature | 2025 Feb
REPOSITORIES: biostudies-literature
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