Di-<i>tert</i>-butyl-diiso-thio-cyanato-tin(IV).

ABSTRACT: The title compound, [Sn(C₄H₉)₂(NCS)₂], which crystallizes with one and a half mol-ecules in the asymmetric unit, represents a new structure type for inter-molecular sulfur⋯tin inter-actions, which is characterized by an anti-parallel (A) arrangement of the dipole moments of the individual mol-ecules. In the resulting zigzag chains, the mol-ecules are related to each other by mirror planes (m) and twofold rotation axes (2), both perpendicular to the propagation plane, while translation is realized via a glide plane in direction of the crystallographic c axis, a combination of symmetry elements unique in the structural chemistry of diorganotin(IV) dihalides and pseudohalides, R ₂SnX ₂

SUBMITTER: Kamrowski A 

PROVIDER: S-EPMC11799781 | biostudies-literature | 2025 Jan

REPOSITORIES: biostudies-literature