Thermodynamic and Kinetic Studies of Mononuclear Non-Heme High-Valent (FeO)²⁺ Complexes.

ABSTRACT: Mononuclear nonheme high-valent (FeO)²⁺ complexes participate in many enzymatic oxidation-reduction cycles in a living body and play a key role in organic synthesis. The concept of molecular ID (molecular identities) was proposed and applied in our previous work; it covers all thermodynamic data for compounds containing an active carbon-hydrogen bond: oxidation potential, hydride anion affinity, proton affinity, and hydrogen atom affinity. To facilitate quantitative analysis of the physical organic chemistry and molecular biology properties of (FeO)²⁺ complexes, the molecular identities and reaction thermodynamic platform of representative complexes were established based on the thermodynamic data, such as (N4Py)(FeO)²⁺ and (Bn-TPEN)(FeO)²⁺, and

SUBMITTER: Chen BL 

PROVIDER: S-EPMC11800002 | biostudies-literature | 2025 Feb

REPOSITORIES: biostudies-literature