Structural Basis of Ultralow Capacitances at Metal-Nonaqueous Solution Interfaces.

ABSTRACT: Metal-nonaqueous solution interfaces, a key to many electrochemical technologies, including lithium metal batteries, are much less understood than their aqueous counterparts. Herein, on several metal-nonaqueous solution interfaces, we observe capacitances that are 2 orders of magnitude lower than the usual double-layer capacitance. Combining electrochemical impedance spectroscopy, atomic force microscopy, and physical modeling, we ascribe the ultralow capacitance to an interfacial layer of 10-100 nm above the metal surface. This nanometric layer has a Young's modulus around 2 MPa, which is much softer than typical solid-electrolyte interphase films. In addition, its AC ionic conductivity is 4-to-5 orders of magnitude lower than that of the bulk electrolyte. The temperature dependencies of

SUBMITTER: Chen J 

PROVIDER: S-EPMC11803618 | biostudies-literature | 2025 Feb

REPOSITORIES: biostudies-literature