Integrating ex situ biomimetic extraction analyses into contaminated sediment assessment and management decisions.

ABSTRACT: This study evaluated a novel ex situ passive sampling biomimetic extraction (BE) method to estimate toxic potency in sediments. Gas chromatography with flame ionization detection (GC-FID) analysis of polydimethylsiloxane fibers equilibrated with field sediments was used to quantify bioavailable polyaromatic hydrocarbons (PAHs) and other unresolved, site-specific contaminant mixtures. This method is biomimetic because contaminants partition to the fiber based on hydrophobicity and abundance, and GC-FID quantification accounts for all constituents absorbed to the fiber that may contribute to toxicity. This measurement was compared with conventional approaches that rely on bulk sediment or porewater measurements of a targeted suite of PAHs. The specific objectives of the study were to (1) des

SUBMITTER: Parkerton TF 

PROVIDER: S-EPMC11804877 | biostudies-literature | 2025 Jan

REPOSITORIES: biostudies-literature