Infrared Ion Spectroscopy of Gaseous [Cu(2,2'-Bipyridine)₃]²⁺: Investigation of Jahn-Teller Elongation Versus Compression.

ABSTRACT: Symmetry breaking is ubiquitous in chemical transformations and affects various physicochemical properties of materials and molecules; Jahn-Teller (JT) distortion of hexa-coordinated transition-metal-ligand complexes falls within this paradigm. An uneven occupancy of degenerate 3d-orbitals forces the complex to adopt an axially elongated or compressed geometry, lowering the symmetry of the system and lifting the degeneracy. Coordination complexes of Cu²⁺ are known to exhibit axial elongation, while compression is far less common, although this may be due to the lack of rigorous experimental verification. Here, we present the gas-phase vibrational spectrum of the archetypal [Cu(2,2'-bipyridine)₃]²⁺ ionic complex, obtained by infrared multiple-photon dissocia

SUBMITTER: Munshi MU 

PROVIDER: S-EPMC11808781 | biostudies-literature | 2025 Feb

REPOSITORIES: biostudies-literature