Copper-anchored polysulfonamide-modified UiO-66-NH₂/sodium alginate nanocatalyst for sustainable synthesis of 1,2,3-triazoles.

ABSTRACT: An effective nanocomposite comprising a metal-organic framework and porous polysulfonamide-sodium alginate (SA-PS) was developed for phenyl triazole production. The Cu(i) ions were uniformly distributed on the as-prepared UiO-66-NH₂@SA-PS matrix, coordinated by sulfonamide groups in a bidentate bridging pattern (UiO-66-NH₂@SA-PS/CuI). The nanocatalyst UiO-66-NH₂@SA-PS/CuI demonstrated exceptional performance in the synthesis of 1,2,3-triazole derivatives, facilitating high product yields in the reaction of various aryl boronic acids, phenylacetylene, and sodium azide under mild conditions.

SUBMITTER: Koosha S 

PROVIDER: S-EPMC11808793 | biostudies-literature | 2025 Mar

REPOSITORIES: biostudies-literature