Lignin- and Cellulose-Derived Sustainable Nanofiltration Polyelectrolyte Membranes.

ABSTRACT: Nanofiltration (NF) polymeric membranes are typically made from fossil fuel-derived feedstocks and toxic solvents, requiring a shift to more sustainable materials. This study pioneers the use of two biopolymers-cationic lignin and sodium carboxymethyl cellulose-as polycation and polyanion, respectively, to fabricate a polyelectrolyte membrane (PEM) via the layer-by-layer method with water as the sole solvent and on a poly(ether sulfone) (PES) support. At a transmembrane pressure of 2 bar, the pure water permeance was 6 LMHB (L/m² h bar) for 5 bilayers with a 96% rejection for positively charged methylene blue and 93% for negatively charged reactive orange-16, with a mass balance above 90%, indicating minimal adsorption on the membrane surface. The molecular weight cutoff (MWCO)

SUBMITTER: Sadare O 

PROVIDER: S-EPMC11816010 | biostudies-literature | 2025 Feb

REPOSITORIES: biostudies-literature