Three New Multifunctional Supramolecular Compounds Based on Keggin-Type Polyoxoanions and 3,5-di(1H-Imidazol-1-yl)benzoic Acid: Syntheses, Structures, and Properties.

ABSTRACT: Three new inorganic-organic hybrid compounds, (H₃DIBA)₂·SiMo₁₂O₄₀·H₂O (1), (H₃DIBA)₂·SiW₁₂O₄₀·H₂O (2), and [(H₂DIBA)(H₃DIBA)]·PMo₁₂O₄₀·2H₂O (3) (HDIBA = 3,5-di(1H-imidazol-1-yl)benzoic acid) were synthesized by the hydrothermal method. The structures were characterized by single-crystal X-ray diffraction, elemental analysis, powder X-ray diffraction, infrared spectroscopy, and thermogravimetric analysis. These three compounds are all 3D supramolecular structures formed by Keggin-type polyoxometalate anions and HDIBA through intermolecular weak interactions, which have been studied via Hirshfeld surface anal

SUBMITTER: Lv Y 

PROVIDER: S-EPMC11820590 | biostudies-literature | 2025 Jan

REPOSITORIES: biostudies-literature