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Development of a Highly Durable Photocatalytic CO₂ Reduction Using a Mn-Complex Catalyst: Application of Selective Photosplitting of a Mn(0)-Mn(0) Bond.

ABSTRACT: fac-[Mn^I(diimine)(CO)₃(L)]^0/+ has attracted significant attention as a catalyst for the photocatalytic reduction of CO₂. However, in such photocatalytic systems, the photoexcitation of Mn complexes and reaction intermediates induces their decomposition, which lowers the durability of these systems. In this study, we clarified the primary process whereby the Mn complex catalyst decomposes during the photocatalytic reaction. Based thereupon, we successfully constructed a highly durable photocatalytic system, of which the turnover number of formate (TON_HCOO-) exceeded 1700 when fac-[Mn^I(bpy)(CO)₃((OC(O)OC₂H₅N(C₂H₅OH)₂) (Mn-CO₂

SUBMITTER: Koizumi H

PROVIDER: S-EPMC11848913 | biostudies-literature | 2025 Feb

REPOSITORIES: biostudies-literature

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Development of a Highly Durable Photocatalytic CO₂ Reduction Using a Mn-Complex Catalyst: Application of Selective Photosplitting of a Mn(0)-Mn(0) Bond.

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Dataset Information

Development of a Highly Durable Photocatalytic CO2 Reduction Using a Mn-Complex Catalyst: Application of Selective Photosplitting of a Mn(0)-Mn(0) Bond.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Development of a Highly Durable Photocatalytic CO₂ Reduction Using a Mn-Complex Catalyst: Application of Selective Photosplitting of a Mn(0)-Mn(0) Bond.