Adamantane-Type Nitridophosphate Phosphors AE_xLi_10-2xP₄N₁₀ : Eu2⁺ via Medium-Pressure Ion-Exchange Reactions.

ABSTRACT: Nitridophosphates have emerged as promising host compounds in the field of solid-state lighting. Their industrial relevance has increased significantly, mainly due to recent advances in synthetic approaches under medium-pressure (MP) conditions, including ammonothermal synthesis and hot isostatic pressing (HIP). In this study, we report on the synthesis and characterization of the quaternary representatives Ca_xLi_10-2xP₄N₁₀ (x=2, 2.7, 4) and Sr₃Li₄P₄N₁₀, prepared via a simplified ion exchange reaction under MP conditions, starting from the nitridophosphate-based lithium ion conductor Li₁₀P₄N₁₀. The synthesis route allowed for the preservation of the anionic [P₄

SUBMITTER: Pritzl RM 

PROVIDER: S-EPMC11848985 | biostudies-literature | 2025 Feb

REPOSITORIES: biostudies-literature