Optimizing selectivity via steering dominant reaction mechanisms in steam reforming of methanol for hydrogen production.

ABSTRACT: Enhancing selectivity towards specific products remains a pivotal challenge in energy catalysis. Herein, we present a strategy to refine selectivity via pathway optimization, exemplified by the rational design of catalysts for methanol steam reforming. Over traditional Pd/ZnO catalysts, the direct decomposition of key intermediates CH₂O* into CO and H₂ on PdZn alloys competes with the oxidation of CH₂O* to CO₂, leading to inferior selectivity in product distribution. To address this challenge, Cu is introduced to modify the catalytic dynamics, lowering the dissociation energy barrier of water to provide more active hydroxyl groups for the oxidation of CH₂O*. Simultaneously, the CO desorption energy barrier on PdCu alloys is elevated, t

SUBMITTER: Zhang M 

PROVIDER: S-EPMC11850624 | biostudies-literature | 2025 Feb

REPOSITORIES: biostudies-literature