One-Step Fabrication of Poly(vinylidene Fluoride-Co-Hexafluoropropylene)/Perfluorodecyltriethoxysilane Fibrous Membranes with Waterproof, Breathable, and Radiative Cooling Properties.

ABSTRACT: Functional membranes with waterproof, breathable, and thermal regulation capabilities are increasingly sought after across various industries. However, developing such functional membranes commonly involves complex multi-step preparation processes. Herein, we introduced perfluorodecyltriethoxysilane (FAS) into the poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) solution for one-step electrospinning, successfully fabricating membranes that combine these properties. The hydrophobicity of the PVDF-HFP/FAS membrane was greatly improved with the water contact angle increased from 120.6° to 142.9° and the solar reflectance rising from 72% to 92% due to the presence of fluorocarbon segments. The synergistic effect of enhanced hydrophobicity, small pore size, and elevated solar reflect

SUBMITTER: Hou A 

PROVIDER: S-EPMC11858151 | biostudies-literature | 2025 Feb

REPOSITORIES: biostudies-literature