Ferrocenyl Lawesson's reagent-based porous organic polymers for efficient adsorption-assisted photocatalysis degradation of organic dyes.

ABSTRACT: The adsorption process followed by photodegradation, adsorption-assisted photocatalysis, is an efficient way to achieve an enhanced overall removal of pollutants from wastewater. This aim can be achieved by a new type of metallocene-based porous organic polymers, denoted as Ferrocenyl Lawesson's reagent-metal-organic porous polymers (FcLR-MOPPs), including FcLR-P1 and FcLR-P2, synthesized through 1) synthesis of ferrocene-MOPPs (ferrocene-P1 and ferrocene-P2) through a Friedel-Crafts reaction between dimethoxymethane and ferrocene at two different ratios of 3:1 and 5:1 and 2) reaction of the ferrocene-MOPPs with phosphonium pentasulfide (P₂S₅). The photodegradation efficiencies of methylene blue (MB) and methyl orange (MO) toward FcLR-MOPPs were higher than those of t

SUBMITTER: Asgari S 

PROVIDER: S-EPMC11883355 | biostudies-literature | 2025 Feb

REPOSITORIES: biostudies-literature