Beyond scaling relations in electrocatalysis: unifying concepts from molecular systems and metallic surfaces.

ABSTRACT: Transitioning the chemical industry away from fossil fuels is a critical goal that requires the adoption of alternative, non-fossil carbon feedstocks. The electrochemical CO₂ reduction reaction, driven via renewable-derived electricity, represents an unparalleled technology that uses CO₂ as a C₁-building block to generate industrially relevant products. Although many electrocatalytic systems have demonstrated promising activities in producing a wide range of products, challenges remain in controlling the product selectivity and reducing the operating overpotential for large-scale applications. This Perspective outlines recent efforts in designing tailored microenvironments in electrocatalytic systems to boost their selectivity and energy efficiency.

SUBMITTER: Kolding KN 

PROVIDER: S-EPMC11887130 | biostudies-literature | 2025 Apr

REPOSITORIES: biostudies-literature