Bifunctional additive-driven shape transitions of block copolymer particles through synergistic quaternization and protonation.

ABSTRACT: Block copolymer (BCP) particles with tailored shapes and nanostructures hold promise for applications in cell adhesion, photonic system, and energy storage due to their unique optical and rheological properties. Conventional approaches relying on surfactant-mediated self-assembly often limit particle geometries to simple structures. Herein, we present a versatile approach to expand the morphology of poly(styrene-block-2-vinylpyridine) (PS-b-P2VP) BCP particles through the incorporation of 9-bromononanoic acid (BNA), a bifunctional additive that facilitates synergistic quaternization and protonation. Increasing the BNA-to-2VP molar ratio enhances P2VP hydrophilicity and decreases the pH value, driving dramatic shape transitions from onion-like spheres to tulip bulbs, ellipsoid

SUBMITTER: Tan Z 

PROVIDER: S-EPMC11907369 | biostudies-literature | 2025 Apr

REPOSITORIES: biostudies-literature