Effective Electron-Vibration Coupling by Ab Initio Methods.

ABSTRACT: The description of electron-phonon coupling in materials is complex, with varying definitions of coupling constants in the literature and different theoretical approaches available. This article analyzes different levels of theory to introduce and compute these coupling constants. Within the quasi-particle picture, we derive an effective linear-coupling Hamiltonian, describing the interaction of electronic quasi-particles with vibrations. This description allows a comparison between coupling constants computed using density functional theory and higher-level quasi-particle approaches by identifying the Kohn-Sham potential as an approximation to the frequency-independent part of the self-energy. We also investigate their dependence on the exchange-correlation (XC) functional. Despite signif

SUBMITTER: Dorfner MFX 

PROVIDER: S-EPMC11912215 | biostudies-literature | 2025 Mar

REPOSITORIES: biostudies-literature