Interfacing Flexible Design and Social Self-Sorting Enables Comprehensive Control over Photophysical and Self-Assembly Properties of Supramolecular Polymers.

ABSTRACT: Supramolecular self-assembly offers an intriguing approach to construct microarchitectures, which combine properties of their molecular constituents with dynamic supramolecular features. Control over intermolecular interactions and their resulting properties can sometimes be achieved by targeted design. However, it is often unfeasible to transfer the insights gained from a specific supramolecular synthon to another chromophore without tedious synthetic work guided by trial and error. Herein we demonstrate how a flexible molecular design approach enables access to a diverse library of photophysical properties, which can be further diversified by social self-sorting strategies using a second supramolecular building block as a modulator. By intercalation into the supramolecular polymer the mo

SUBMITTER: Baumer N 

PROVIDER: S-EPMC11912333 | biostudies-literature | 2025 Mar

REPOSITORIES: biostudies-literature