Optimizing Nickel(II) Complex Catalysts for High-Yield Oligomerization of Cyclohexyl Isocyanide.

ABSTRACT: Isocyanides, due to the divalent carbon atom present in their structure, are among the most reactive groups of compounds in organic chemistry. Unfortunately, although according to the literature they do not have acute toxicity, they have a very unpleasant odor that makes it difficult to collaborate with them. However, despite the properties mentioned, reactions of isocyanides often lead to a variety of functional materials. In this article, we present a modified method for obtaining isocyanide-based polymers that significantly reduce the release of their hazardous vapors into the environment. For the study, a series of nickel(II) metal ion complex compounds containing organic ligands (e.g., 2,2'-bipyridyl, 1,10-phenanthroline, and diglycolate anion) were synthesized and used as catalysts i

SUBMITTER: Pawlak M 

PROVIDER: S-EPMC11920947 | biostudies-literature | 2025 Mar

REPOSITORIES: biostudies-literature