Synthesis and Photophysical Properties of AIE-Type Carbazole-Capped Triphenylmethyl Organic Radicals Featuring Non-Aufbau Electronic Structure and Enhanced Photostability.

ABSTRACT: In this study, we report two novel donor-acceptor (D-A•)-type triphenylmethyl radicals, TTM-1TPE-2Cz and TTM-2TPE-2Cz, synthesized by integrating an aggregation-induced emission (AIE)-active 2-(1, 2, 2-triphenylethenyl)-9H-carbazole (TPE-2Cz) donor with tris(2,4,6-trichlorophenyl)methyl (TTM) radical core. Despite the AIE unit's conventional ACQ-suppressing capability, both radicals exhibit complete emission quenching in solid/solution states but demonstrate 655 nm red emission in polymethyl methacrylate (PMMA)-doped films. Theoretical and experimental analyses reveal that the flexible TPE moiety unexpectedly enhances non-radiative decay while establishing a non-Aufbau electronic configuration through its strong electron-donating nature (-5.16 eV HOMO vs. -5.75 eV SOMO). Remarkably, these

SUBMITTER: Parida H 

PROVIDER: S-EPMC11944396 | biostudies-literature | 2025 Mar

REPOSITORIES: biostudies-literature